Research Article | | Peer-Reviewed

Petrography and Geochemistry of Syenogranites and Gabbronorites from the Niergui Massif, Guéra Province, Chad

Received: 26 February 2026     Accepted: 16 March 2026     Published: 23 April 2026
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Abstract

The Niergui Massif, located at the southern margin of the Sahara Metacraton, represents a poorly documented portion of the Pan-African basement in Chad. This study integrates petrographic and geochemical analyses of syenogranites and gabbronorites to better constrain their nature, origin, and the magmatic processes involved in basement formation. The syenogranites are strongly potassic calc-alkaline, weakly peraluminous, and ferroan, whereas the gabbronorites are metaluminous and moderately differentiated. Major, trace, and rare-earth element geochemistry indicates a progressive magmatic evolution: gabbronorites reflect a primitive mantle source, while syenogranites show enrichment in incompatible elements and differentiation toward crustal magmas. Sr/Y and Rb/Sr ratios, as well as Eu anomalies, suggest that syenogranites formed from a mixture of enriched mantle and crustal sources, whereas gabbronorites are weakly differentiated and mantle-derived. Nb/Zr vs. Zr diagrams and zircon saturation temperatures (700–850°C) indicate that magma crystallization involved both fractional crystallization and partial melting. Tectonic discrimination diagrams (Ta vs. Yb, Rb vs. Yb+Ta) confirm a subduction setting followed by a syn- to post-collisional phase, consistent with the Pan-African dynamics between the Congo Craton and the Adamawa-Yadé block. These results indicate that the Niergui Massif exemplifies a bimodal magmatic system, characterized by mantle–crust interaction, partial melting, and fractional crystallization. The complexity of geochemical signatures reflects local variations and multiple stages of magmatic evolution from mantle to differentiated crustal magmas. This study provides a solid framework for understanding Pan-African geodynamics in the Guéra region and contributes to the characterization of the Neoproterozoic basement of the Sahara Metacraton.

Published in Earth Sciences (Volume 15, Issue 2)
DOI 10.11648/j.earth.20261502.13
Page(s) 109-124
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2026. Published by Science Publishing Group

Keywords

Syenogranites, Gabbronorites, Bimodal Magmatism, Subduction, Guéra, Pan-African

1. Introduction
Located at the southern margin of the Sahara Metacraton, the central Chadian massif of Guéra is poorly documented due to the scarcity of outcrops. It is composed of metamorphic and magmatic rocks associated with the collision between the Congo–São Francisco Craton and the Sahara Metacraton. The Neoproterozoic Guéra basement is dominated by granitoids and mafic enclaves . Several studies suggest that these rocks result from mixing between mantle-derived and crustal magmas, reflecting the complexity of the geodynamic processes involved . Further south, in the Melfi Massif, syenites and granites enriched in alkalis and light rare earth elements, associated with positive Eu anomalies, indicate the involvement of partial melting of garnet-amphibolite sources with a contribution from metasomatized mantle . Magmatic activity in this region lasted for approximately 50 Ma, from 595 to 545 Ma , while U–Th–Pb zircon ages ranging from 1.9 Ga to 580 Ma document Pan-African crustal recycling. The oldest granites (595 ± 8 Ma and 589 ± 6 Ma) are metaluminous to peraluminous, magnesian, with alkaline to calc-alkaline signatures, whereas the younger granites (≤ 570 Ma) are peraluminous, ferriferous, alkali-calcic, and post-collisional . Two generations of post-collisional granites are distinguished: first, arc-type hornblende–biotite granites (~595 Ma) derived from partial melting of subduction-modified mantle; second, biotite granites (~590 Ma) emplaced during crustal relaxation following an oblique collision . A second post-collisional magmatic phase, after crustal thinning, eventually produced granites around 560 Ma . Despite these advances, the central Chadian massif remains largely unexplored, and the nature, origin, and evolution of the Guéra formations remain key questions. This knowledge gap limits the understanding of Pan-African dynamics in this portion of the orogen. The present study aims to address this gap by characterizing the formations of Niergui and its surroundings through a petrographic and geochemical approach, in order to constrain their origin and improve understanding of the magmatic processes involved in the construction of the Pan-African Chadian basement.
2. Geological Setting
Figure 1. Location of the study area within the geological framework of North-Central Africa (modified after . The inferred boundary of the Saharan Metacraton is drawn after Abdelsalam et al. .
The Pan-African orogeny, initially interpreted as a simple reactivation of Archean structures , is now widely recognized as a major Neoproterozoic thermo-tectonic event that profoundly shaped Gondwana between ~700 and 500 Ma, with a peak of activity around 600 ± 100 Ma . In Central Africa, this orogeny is notably expressed by the development of the Oubanguides belt, characterized by large sublatitudinal (E–W) shear zones and high-grade metamorphism . In Chad, the Precambrian basement inherited from this orogeny lies within a complex junction zone between the Congo Craton, the Eastern Nigerian domain, and the Saharan Metacraton . The Chadian Central Massif, including the Guéra, Kenga, and Melfi massifs, occupies a strategic geodynamic position between the Chad Craton, the Darfur block, and the Congo Craton (Figure 1). This setting makes it a key domain for investigating crustal evolution and crust–mantle interactions during the Pan-African orogeny . The earliest geological descriptions of the Chadian Central Massif date back to the works of Freydenberg and Lacroix , later complemented by the detailed studies of Vincent . These authors highlighted the existence of three successive major magmatic cycles, referred to as gA, gB, and gC, as well as the occurrence of so-called malgachitic facies, showing affinities with the charnockites of southern India. Subsequent studies also documented a variety of metamorphic rocks, including quartzites, micaschists, gneisses, and tactites, generally occurring as enclaves within granitoid plutons .
Lithologically, the Chadian Central Massif is dominated by intense Pan-African magmatism, mainly represented by granitoids (granodiorites, granites, and charnockites), associated with intermediate to mafic rocks such as diorites and gabbros . These magmatic formations account for nearly 90% of the crustal edifice of the massif. Three main lithological units are classically distinguished: (1) the younger granites, of Pan-African to post-Pan-African age, generally forming prominent reliefs and locally occurring as inselbergs; (2) a heterogeneous granitic complex, predominantly calc-alkaline in composition, widely distributed throughout the massif and commonly characterized by abundant enclaves of older rocks; and (3) the older granodioritic series, occurring as bands and enclaves, comprising granodiorites, diorites, and locally gabbros, and displaying charnockitic affinities comparable to the malgachitic series described by Lacroix . Finally, this assemblage is crosscut by late mafic intrusions, represented by small gabbroic bodies and doleritic to microgabbroic dykes, attesting to magmatic activity subsequent to the emplacement of the main Pan-African granitoids .
3. Methodology
The present study is based on an integrated methodological approach combining field observations, petrographic analyses, and geochemical investigations in order to characterize the nature, composition, and geological evolution of the study area. Fieldwork involved direct observations of outcrops, including macroscopic descriptions of lithologies, structural mapping, and the collection of representative rock samples. These observations allowed refinement of the lithological typology, spatial distribution, and contact relationships between the different rock units. Petrographic investigations were carried out on thin sections prepared according to standard procedures at the Institute of Geological and Mining Research (IRGM), Yaoundé. Microscopic observations were conducted under polarized light to identify mineral assemblages, textures, and microstructures characteristic of the studied rocks. For geochemical analyses, each sample was crushed and homogenized. Approximately 25 g of powder, with an average grain size of ~75 µm, were collected, packaged in appropriate containers, and sent to ACTLABS laboratories (Ontario, Canada) and ALS Geochemistry (Johannesburg, South Africa). Major elements and selected trace elements were analyzed by inductively coupled plasma–optical emission spectrometry (ICP-OES), whereas trace elements and rare earth elements were determined by inductively coupled plasma–mass spectrometry (ICP-MS). In total, twenty-four (24) rock samples (labelled ENGxx) were collected during this study (Figure 8). Of these, thirteen (13) samples were selected for thin-section preparation, and five (5) representative samples were retained for whole-rock geochemical analyses.
4. Results
4.1. Petrography
Petrographic results indicate that the study area is mainly composed of plutonic rocks, which can be grouped into two major lithological domains: a granitoid domain and a gabbroic domain (Figure 2). The granitoid domain comprises syenogranites, amphibole–biotite monzogranites, biotite monzogranites, quartz–alkali feldspar syenites, and quartz syenites. The gabbroic domain is exclusively represented by gabbronorite.
4.1.1. Field Observations
Granitoids mainly crop out as metric to plurimetric blocks, producing a chaotic landscape typical of granitic boulder fields. Locally, these rocks occur as exposed slabs (Figure 3a). In outcrop, they are generally light grey in colour and display medium- to coarse-grained textures. Amphibole–biotite monzogranite is locally crosscut by discordant veins (Figure 3b). These veins, centimetric in thickness, are characterized by a pinkish-grey colour, metric to plurimetric continuity and fine- to medium-grained textures. Their relatively homogeneous internal structure, combined with their crosscutting geometry and finer grain size compared to the host rock, suggests a late-stage emplacement. Quartz–alkali feldspar syenites crop out as blocks ranging from 0.5 to 8 m in size. They are distinguished by the presence of orthoclase phenocrysts, a pinkish-grey colour, and a dark weathering patina. Gabbronorite occurs mainly as enclaves within the granitic bodies, particularly within syenogranites (Figure 4b). These enclaves display characteristic sigmoidal morphologies, with sizes ranging from centimetric to metric. In addition, metric to plurimetric gabbronorite blocks were also observed (Figure 4a), indicating heterogeneity in emplacement modes. The rock is dark grey to black in colour, with fine- to medium-grained textures reflecting its high mafic mineral content.
Figure 2. Geological map of the study area.
4.1.2. Microscopic Observations
Under the microscope, granitoids display a porphyroid granular texture (Figure 3d). Their mineral assemblage is dominated by alkali feldspar, quartz, plagioclase, biotite, and amphibole. Accessory minerals include opaque phases, zircon, apatite, sphene (titanite), and locally chlorite. Alkali feldspars are generally rectangular to sub-rectangular in shape and are represented by orthoclase and microcline, with orthoclase being predominant. Some orthoclase crystals show microfractures filled with quartz, perthitic textures, and locally Carlsbad twinning (Figure 3c). Microcline commonly exhibits sericitization. Quartz is generally polycrystalline (Figure 3d) and occurs in two main forms: (i) small subgrains, commonly included within feldspars or located along their margins, and (ii) quartz ribbons with undulose extinction, reaching up to 0.4 mm in length and 0.2 mm in width, indicative of intracrystalline deformation. Plagioclase occurs as euhedral to subhedral crystals, commonly twinned, with mechanical twins arranged in wedge- or spindle-shaped patterns. Some crystals contain quartz inclusions. Biotite occurs as elongated crystals (Figure 3e) or as xenomorphic grains with irregular outlines (Figure 3d). It locally contains inclusions of opaque minerals and zircon and shows partial alteration to chlorite (Figure 3e). In some cases, biotite molds alkali feldspar crystals (Figure 3c). Amphiboles are generally subhedral. Some crystals contain inclusions of opaque minerals, whereas others display partial destabilization to chlorite, reflecting late-stage alteration or re-equilibration processes. All samples belonging to the gabbroic domain are gabbronoritic in nature and are more precisely classified as clinopyroxene-bearing norites according to the P–Opx–Cpx (Plagioclase-Orthopyroxene-Clinopyroxene) diagram of Streckeisen . They are characterized by granular to doleritic textures, typically intergranular (Figure 4f). The mineral assemblage is dominated by plagioclase, orthopyroxene, and clinopyroxene, associated with biotite, orthoclase, amphibole, and opaque minerals. A notable difference is observed among samples: some (ENG6 and ENG25) contain interstitial xenomorphic quartz located along the margins of major crystals, whereas others (ENG9 and ENG19) lack any quartz phase.
Plagioclase crystals occur as elongated laths, reaching up to 1.6 mm in length and approximately 0.5 mm in width (Figure 4f). These crystals are commonly intergrown, imparting a texture characteristic of relatively rapid cooling. Interstices between plagioclase crystals are generally occupied by amphiboles and opaque minerals (Figure 3d). Some plagioclase crystals contain inclusions of pyroxene and opaque minerals (Figure 4e) and locally show sericitic alteration. Mechanical twins, in the form of spindle- or wedge-shaped patterns, are also observed (Figure 4f). Pyroxenes in the gabbronorite are predominantly xenomorphic. Orthopyroxene (Opx) is the dominant pyroxene, whereas clinopyroxene (Cpx) occurs in lower proportions, generally occupying interstitial spaces between plagioclase crystals and in proximity to orthopyroxene grains.
4.2. Geochemistry
In order to characterize the main geochemical properties, five representative whole-rock samples were analyzed (Tab. 1): two syenogranites (ENG10 and ENG16) and three gabbronorites (ENG9, ENG19, and ENG25). The results were interpreted using typological binary diagrams and geochemical discrimination plots, allowing a better assessment of the nature and origin of the studied units.
Figure 3. Field photographs and photomicrographs of granitoids: (a) Slab outcrop and block of syenogranite at Niergui; (b) Slab outcrop of amphibole–biotite monzogranite crosscut by a greyish-pink dyke; (c) Photomicrograph showing a coarse-grained porphyritic texture; (d) Thin-section view highlighting perthitic structure and microfractures; (e) Photomicrograph showing a zircon crystal included in biotite and biotite destabilization into chlorite; (f) Thin-section view highlighting sphene (titanite) crystals adjacent to alkali feldspars.
Figure 4. Field photographs and photomicrographs of gabbronorite: (a) Block outcrop; (b) Gabbronorite enclave within the surrounding granites; (c) Hand sample of gabbronorite; (d) Opaque minerals and biotite inclusions within plagioclase; (e) Thin-section view highlighting inclusions of pyroxene and opaque minerals within plagioclase; (f) Photomicrograph showing a coarse-grained to intergranular doleritic texture.
4.2.1. Major Elements
Table 1 presents whole rocks major eements content and normative composition. The syenogranites are characterized by high SiO2 (69.00–70.00 wt%) and Al2O3 (14.40–15.25 wt%) contents. K2O (4.78–5.43 wt%) and Na2O (3.33–3.81 wt%) concentrations are also high, whereas Fe2O3 (2.42–3.05 wt%), MnO (0.04 wt%), P2O5 (0.10–0.22 wt%), TiO2 (0.34–0.39 wt%), MgO (0.50–0.73 wt%), and CaO (1.78–1.88 wt%) remain low. The K2O/Na2O ratio ranges from 1.43 to 1.44, indicating a strongly potassic composition.
Gabbronorites display moderate SiO2 (47.30–51.00 wt%) and Al2O3 (14.35–14.95 wt%) contents, and high concentrations of Fe2O3 (13.40–13.60 wt%), CaO (6.77–7.77 wt%), MgO (3.90–6.22 wt%), TiO2 (2.34–2.88 wt%), MnO (0.17–0.18 wt%), and P2O5 (0.78–1.26 wt%), whereas K2O (1.35–2.18 wt%) and Na2O (2.85–2.92 wt%) are relatively low. CIPW normative calculations for the syenogranites yield the following proportions: quartz 21.85–26.11%, orthoclase 28.95–32.26%, albite 28.88–32.41%, anorthite 8.23–8.29%, and hypersthene 3.50–4.80%. Accessory normative phases include magnetite (0.08–0.82%), ilmenite (0.65–0.76%), and apatite (0.22–0.49%). Normative corundum is present in very low amounts (0.77%). The very high differentiation index (DI = 83.93–86.51%) highlights the advanced magmatic evolution of the syenogranites. In the gabbronorites, normative corundum is absent, indicating a clearly metaluminous signature. Sample ENG9 lacks normative quartz but contains a considerable amount of normative olivine (5.40%), suggesting a slightly more basic composition. Normative proportions reveal a dominance of pyroxenes, with diopside ranging from 5.63 to 9.36% and hypersthene from 20.04 to 21.21%. Feldspars are represented by orthoclase (8.55–13.19%), albite (25.12–25.86%), and anorthite (20.08–25.31%), with normative quartz amount of 1.22 and 3.80% for ENG19 and ENG25 respectively. Accessory phases include ilmenite (4.55–5.60%), magnetite (2.37–2.51%), and apatite (1.83–2.82%). The moderate differentiation index (DI = 34.32–42.29%) indicates that the gabbronorites are moderately differentiated.
(i). Rock Classification
The multicational R1–R2 diagram classifies the granitic rocks as monzogranites, whereas the gabbroic rocks plot within the gabbrodiorite field (Figure 5a). The Q′–ANOR diagram confirms the syenogranitic, monzogranitic, and gabbroic classifications for the respective samples (Figure 5b).
(ii). Magmatic Affinity
In the TAS diagram , syenogranites and gabbronorites plot within the acidic and basic fields, respectively (Figure 6a). Their position below the dividing line of Irvine and Baragar indicates affiliation with the subalkaline series. Complementary analysis using the AFM diagram shows that all samples belong to the calc-alkaline series (Figure 6b).
Figure 5. Classification of Niergui studied rocks. (a) R1–R2 cationic diagram of De La Roche et al. , where R1 = 4Si − 11(Na + K) − 2(Fe + Ti) and R2 = 6Ca + 2Mg + Al; (b) Normative Q′–ANOR diagram of Streckeisen and Le Maitre , where ANOR = 100 × An/(An + Or) and Q′ = 100 × Q/(Q + Or + Ab + An).
This classification is further supported by the K2O vs. SiO2 diagram of Le Maitre et al. , which highlights the overall calc-alkaline affinity of the rocks (Figure 6c). More specifically, the syenogranites display a strongly potassic calc-alkaline signature evolving toward the shoshonitic field, whereas the gabbronorites exhibit moderate to slightly elevated potassium contents. Finally, the FeOₜ/(FeOₜ + MgO) diagram indicates that the syenogranites plot within the ferroan field, whereas the gabbronorites are magnesian to slightly ferroan, close to the boundary between these two domains (Figure 6d).
In the A–B cationic diagram , the syenogranites fall within field III, characteristic of peraluminous rocks, whereas the gabbronorites occupy field IV, corresponding to metaluminous rocks (Figure 7a). The A/NK vs. A/CNK diagram (; Figure 7b) confirms this distinction. The syenogranites are weakly peraluminous, plotting close to the boundary with the metaluminous domain, and are assigned to I-type granites. The gabbronorites plot clearly within the metaluminous field, indicating low alumina saturation consistent with an I-type affinity.
Figure 6. Magmatic affinities of the studied rocks: (a) Na2O + K2O vs. SiO2 diagram ; (b) AFM diagram ; (c) K2O vs. SiO2 diagram ; (d) FeO/(MgO + FeO) vs. SiO2 diagram .
Table 1. Whole rock major elements, normative composition and selected ratios.

Rock type

Syenogranite

Gabbronorite

Sample

ENG16

ENG10

ENG25

ENG9

ENG19

SiO2

70.00

69.00

51.00

48.80

47.30

TiO2

0.34

0.39

2.88

2.34

2.35

Al2O3

15.25

14.40

14.35

14.95

14.8

Fe2O3t

2.42

3.05

13.4

13.55

13.6

MnO

0.04

0.04

0.17

0.18

0.18

MgO

0.50

0.73

3.90

6.22

3.48

CaO

1.78

1.88

6.77

7.53

7.77

Na2O

3.81

3.33

2.92

2.90

2.85

K2O

5.43

4.78

2.18

1.52

1.35

P2O5

0.10

0.22

1.26

0.89

0.78

LOI

0.67

0.87

0.70

1.07

0.39

Total

100.34

98.69

99.53

99.95

94.85

A/CNK

1.38

1.44

1.21

1.25

1.24

A/NK

1.65

1.78

2.81

3.38

3.52

K2O/Na2O

1.43

1.44

0.75

0.52

0.47

K2O+Na2O

9.24

8.11

5.10

4.42

4.20

CaO/Na2O

0.47

0.56

2.32

2.60

2.73

Al2O3/TiO2

44.85

36.92

4.98

6.39

6.30

Mg*

34

38

40

51

37

Normative composition

Quartz

21.85

26.11

3.80

-

1.22

Orthose

32.26

28.95

13.19

9.20

8.55

Albite

32.41

28.88

25.30

25.12

25.86

Anorthite

8.29

8.23

20.08

23.84

25.31

Diopside

-

-

5.63

7.47

9.36

Hypersthène

3.50

4.80

21.21

20.04

20.57

Olivine

-

-

-

5.40

-

Magnétite

0.75

0.96

2.37

2.39

2.51

Ilménite

0.65

0.76

5.60

4.55

4.79

Corindon

0.08

0.82

-

-

-

Apatite

0.22

0.49

2.82

1.99

1.83

TOTAL

100.00

100.00

100.00

100.00

100.00

DI

86.51

83.93

42.29

34.32

35.64

4.2.2. Trace Elements and Rare Earth Elements
The syenogranites are characterized by very high Ba (1440–1995 ppm) and Rb (149.4–180 ppm) contents (Tab. 2), reflecting strong enrichment in elements compatible with K-feldspar. Sr (548–825 ppm) and Zr (182–206 ppm) contents are moderate to relatively high, whereas Sc (1.9–3.9 ppm), Cr (12–13 ppm), Y (10.8–20.3 ppm), and V (24–37 ppm) contents remain low. Gabbronorites also display high Ba contents (796–1216 ppm), slightly lower than those of the syenogranites, but very low Rb contents (32.3–60.2 ppm). Sr (523–596 ppm) and Zr (241–513 ppm) are moderate, whereas Cr (65–177 ppm), V (195–209 ppm), Sc (27–28.4 ppm), and Y (34.1–56.9 ppm) are obviously higher than in the syenogranites, indicating a more primitive signature enriched in elements associated with mafic minerals. Primitive mantle–normalized multi-element diagrams show distinct trends for the two rock types. Syenogranites (Figure 8a) display negatively sloping patterns, indicating enrichment in large-ion lithophile elements (LILE) relative to high-field-strength elements (HFSE), with pronounced peaks and troughs. Positive anomalies are observed for Ba, U, K, Sr, Zr, Hf, Ti and Tm, whereas negative anomalies occur for Th, Nb, Pr, Nd and Er. Gabbronorites (Figure 8a) also show negative slopes, but with overall higher concentrations than those of the syenogranites. They are characterized by positive anomalies in Cs, Ba, K, La, Nd, Sm, Ti, and Tm, and negative anomalies in Rb, Th, and Sr. Overall, both rock groups are enriched in incompatible elements; however, syenogranites display lower abundances and more irregular patterns, suggesting significant magmatic fractionation and differentiation processes. Total rare earth element contents (ΣREE) in the syenogranites range from 40.95 to 171.59 ppm. Chondrite-normalized REE patterns indicate enrichment in light rare earth elements (LREE) relative to heavy rare earth elements (HREE), with (La/Yb)n ratios of 2.94–25.22. Syenogranites show no significant europium anomaly, with Eu/Eu* values ranging from 0.92 to 1.06 (Figure 8b).
Gabbronorites exhibit higher and more variable ΣREE contents (209.58–431.49 ppm). Their REE patterns are also characterized by LREE enrichment relative to HREE, with (La/Yb)n ratios of 8.68–10.03, and display a slight negative Eu anomaly (Eu/Eu* = 0.73–0.92) (Figure 8b). Overall, syenogranites and gabbronorites share broadly similar geochemical patterns, although gabbronorites are richer in trace elements and REE, reflecting a less differentiated and more primitive magmatic character.
Figure 7. Metaluminous and peraluminous character of the rocks: (a) A–B cationic diagram illustrating the alumina balance , where A = Al − (K + Na + 2Ca) and B = Mg + Fe + Ti; (b) Maniar and Piccoli diagram showing A/NK = Al2O3/(Na2O + K2O) versus A/CNK = Al2O3/(CaO + Na2O + K2O).
Table 2. Trace elements and selected ratios.

Rock type

Syenogranite

Gabbronorite

Sample

ENG16

ENG10

ENG25

ENG9

ENG19

Ba

1995

1440

1300

861

780

Cr

12

13

65

176

177

Rb

180

149.5

60.2

39.1

32.3

Sr

825

548

596

529

523

V

24

37

204

195

209

Y

10.80

20.30

56.90

37.70

34.10

Zr

206

182

513

272

241

Hf

5.07

5.03

11.35

6.43

5.93

Ta

0.60

0.80

1.50

1.10

0.90

W

0.70

1.00

1.30

0.90

0.90

Th

6.91

0.74

4.96

3.45

2.8

U

1.54

1.08

0.84

0.70

0.61

Nb

7.69

7.41

30.50

18.00

16.10

Cs

2.18

2.09

1.61

0.95

0.50

Ga

21.9

22.8

24.9

22.9

22.0

Sn

2.5

5.1

3.3

2.7

2.1

Sc

1.9

3.9

27.3

27

28.4

La

40.4

6.8

77.7

42.8

35.2

Ce

76.7

16.0

172.0

95.0

78.9

Pr

8.63

2.02

22.40

12.50

10.40

Nd

31.6

9.3

94.6

55.4

47.3

Sm

4.56

2.55

17.9

10.35

9.17

Eu

1.30

0.96

4.10

3.09

2.77

Gd

3.28

3.02

15.85

10.45

9.04

Tb

0.38

0.54

2.07

1.34

1.23

Dy

1.98

3.69

11.4

6.97

6.97

Ho

0.35

0.78

2.10

1.45

1.22

Er

0.93

2.1

5.57

3.92

3.53

Tm

0.16

0.29

0.76

0.50

0.47

Yb

1.15

1.66

4.30

3.06

2.91

Lu

0.17

0.24

0.74

0.48

0.47

Sr/Y

76.40

27.00

10.48

14.03

15.34

Nb/Ta

12.82

9.26

20.33

16.36

17.89

Th/Yb

6.01

0.45

1.15

1.13

0.96

Zr/Hf

40.63

36.18

45.20

42.30

40.64

Nb/Zr

0.037

0.04

0.06

0.07

0.07

5. Discussion
5.1. Nature
According to Barbarin , granitoids can be classified into seven types based on their mineralogical assemblages, petrographic and field characteristics, as well as their chemical and isotopic signatures: MPG (muscovite-bearing peraluminous granitoids), CPG (cordierite-bearing peraluminous granitoids), KCG (K-rich calc-alkaline granitoids), ACG (amphibole-rich calc-alkaline granitoids), RTG (ridge tholeiitic granitoids), ATG (arc tholeiitic granitoids), and PAG (peralkaline and alkaline granitoids). The K2O vs. SiO2 diagram of Le Maitre et al. (; Figure 6c) indicates that the Niergui syenogranites are strongly potassic calc-alkaline rocks. According to this classification, they therefore belong to the KCG type. These rocks are also weakly peraluminous and ferroan .
Figure 8. Normallisation diagrams: (a) Primitive mantle-normalized trace element spider diagrams (normalization values from ; (b) Chondrite-normalized rare earth element (REE) patterns .
The Niergui gabbronorites display a calc-alkaline signature with moderate to slightly elevated potassium contents and a metaluminous character, linking them to I-type granitoids. Their relatively low FeOₜ/(FeOₜ + MgO) ratios, as defined by the diagram of Frost et al. (FeOₜ/(FeOₜ + MgO) = 0.67–0.77), indicate a magnesian composition, comparable to that of ACG-type granitoids. This interpretation is supported by the work of Diontar et al. on the Bitkine gabbro-diorites from the Guéra Massif, which exhibit similar geochemical characteristics. The relatively high Sr (>300 ppm) and Ba (>500 ppm) contents, combined with low Rb concentrations, suggest that these rocks correspond to “high-Sr granitoids” according to the classification of Tarney and Jones . Finally, the Sr/Y vs. Y diagram (Figure 9) shows that most samples correspond to typical calc-alkaline rocks. However, one syenogranite sample is distinguished by a Sr/Y ratio greater than 40, indicating an adakitic affinity .
Figure 9. Sr/Y vs. Y discrimination diagram .
Figure 10. Source characteristics of the Niergui formations and surrounding rocks: (a) Nb/Ta vs. Th/Yb diagram; (b) Nb/Ta vs. Zr/Hf diagram. N-MORB, OIB, and primitive mantle values are from McDonough and Sun , whereas upper and lower continental crust values are from Wedepohl .
5.2. Magma Source
The syenogranites from the study area display calc-alkaline, high-K to shoshonitic, ferroan, and weakly peraluminous characteristics. Their petrographic and geochemical compositions meet the criteria of I-type granitoids as defined by Barbarin , suggesting a petrogenesis from a mixed magma source involving both mantle and crustal contributions. Geochemical analysis of the syenogranites and gabbronorites reveals several significant trends. Most samples exhibit Sr/Y ratios ranging from 10.47 to 27, consistent with classical calc-alkaline arc or active-margin magmatism associated with partial melting or differentiation processes . However, one isolated syenogranite sample is distinguished by a high Sr/Y ratio (76.39) and Sr contents exceeding 500 ppm, indicative of adakitic behavior . This signature may result either from derivation from a deep or thickened crustal source, or from specific internal magmatic processes such as the accumulation of Sr-rich phases or relative Y depletion during fractional crystallization . Ba/Sr ratios ranging from 1.49 to 2.63 suggest moderate crustal contamination, consistent with magma interaction with Ba-enriched felsic sources, while the least differentiated magmas retain a mantle-derived component . The syenogranites also show relatively high Rb/Sr ratios (0.22–0.27), typical of crustal-derived rubidium enrichment , whereas the gabbronorites display lower values (0.06–0.10), compatible with a weakly differentiated mantle magma . Nb/Ta vs. Th/Yb and Nb/Ta vs. Zr/Hf diagrams (Figure 10) indicate a progressive magmatic evolution from gabbronorites toward syenogranites, reflecting a transition from a mantle source (primitive mantle or N-MORB-like) toward a crustal signature. This evolution suggests a bimodal system marked by strong mantle–crust interaction, as documented in other Pan-African complexes of Chad . The most likely source is an enriched mantle metasomatized by subduction-related fluids, whose partial melting generated magmas that subsequently evolved through fractional crystallization and crustal contamination. Rare earth element (REE) patterns provide additional constraints. The syenogranites display Eu* values between 0.92 and 1.06, indicating the absence of a significant europium anomaly and limited plagioclase fractionation during crystallization. In contrast, the gabbronorites, with Eu* values ranging from 0.73 to 0.92, show a moderate negative Eu anomaly, which may reflect plagioclase depletion in the source or early fractionation of this mineral phase . Although some features may appear contradictory, an integrated assessment suggests that the syenogranites originated from an enriched mantle source that experienced partial crustal contamination, as evidenced by enrichment in Cs, Ba, K, Ti, and Tm and by pronounced light rare earth element (LREE) enrichment relative to heavy rare earth elements (HREE) . Furthermore, elevated Rb/Sr ratios and exceptionally high Sr/Y values in some samples indicate a significant crustal contribution or localized adakitic magmatism . Overall, the most plausible scenario involves magma generation in a Pan-African geodynamic setting transitional between an active continental arc and a syn- to post-collisional environment , involving a subduction-metasomatized mantle and strong interaction with the continental crust. This interaction accounts for both mantle- and crust-derived signatures, while also explaining local variations related to internal magmatic processes.
Figure 11. (a) Nb/Zr vs. Zr diagram ; (b) Thermal conditions of magma emplacement, showing estimated zircon saturation temperatures .
5.3. Magmatic Processes and Thermodynamic Conditions of Emplacement
The Nb/Zr vs. Zr diagram (Figure 11a) allows discrimination between partial melting and fractional crystallization processes based on the contrasting behavior of two moderately incompatible elements. In the study area, the gabbronorites plot within the fractional crystallization field, displaying moderate to high Zr contents (241–513 ppm) and relatively low Nb/Zr ratios (<20). These features suggest magmatic evolution through progressive fractionation from a mantle-derived basaltic magma, possibly affected by contamination during ascent or crustal residence . In contrast, the syenogranites plot near the boundary between partial melting and fractional crystallization fields, with slightly higher Nb/Zr ratios and lower Zr contents. This distribution supports a crustal origin through partial melting of metasomatized or previously differentiated materials, possibly triggered by the injection of hot mafic magmas .
The overall dispersion of data points reflects a polyphase magmatic evolution involving both differentiated fractional crystallization and multiple partial melting events . The Zr versus (Na + K + 2Ca)/(Al × Si) diagram is used to estimate the thermal conditions of magma emplacement based on zircon saturation temperatures. According to this diagram, both syenogranite and gabbronorite magmas were emplaced at temperatures ranging between approximately 700°C and 850°C (Figure 11b).
5.4. Geotectonic Context
Granitoids are excellent indicators of tectonic evolution, particularly in subduction and collisional settings. According to Taylor and McLennan , granitoids formed in arc environments are enriched in Ba, Th, and U, and depleted in Nb, Sr, Ti, and P, reflecting magmas influenced by metasomatizing fluids and thickened crust. Within the Pan-African context of Cameroon, several studies attribute the emplacement of granitoids to a continental collision between the Congo Craton and the Adamawa-Yadé block. This collision would have caused crustal thickening and partial melting of the lower crust, leading to the emplacement of granitoids between 570 and 640 Ma. Ta vs. Yb and Rb vs. (Yb + Ta) diagrams (; Figure 12) allow discrimination of different tectonic settings. In the study area, these diagrams indicate that all rock units were emplaced in an arc magmatic (subduction) context, with a possible transition toward a collisional (syn-collisional) environment. This suggests that the study area was situated at an active continental margin during the emplacement of these rocks likely influenced by subduction processes . According to Shellnutt et al. , rocks of the Guéra Massif formed during the collision between the Congo–São Francisco Craton and the Sahara Metacraton, with active magmatism spanning approximately 50 Ma (594–545 Ma). Granites were emplaced in a collisional to post-collisional setting, displaying diverse geochemical characteristics consistent with the magmatic evolution observed in the study area.
Figure 12. Tectonic discrimination diagrams after Pearce et al. : (a) Ta (ppm) vs. Yb (ppm); (b) Rb (ppm) vs. (Yb + Ta) (ppm). WPG = within-plate granites; VAG = volcanic arc granites; syn-COLG = syn-collisional granites; ORG = ocean ridge granites.
6. Conclusion
The petrographic and geochemical study of syenogranites and gabbronorites from the Niergui area provides new insights into the nature, origin, and magmatic processes of the Pan-African basement in Chad. The syenogranites are strongly potassic calc-alkaline, weakly peraluminous, and ferroan, whereas the gabbronorites are metaluminous and moderately differentiated. Major, trace, and rare-earth element geochemistry indicates a progressive magmatic evolution from a basal mantle-derived magma toward more differentiated crustal magmas, reflecting mantle–crust interaction in a bimodal setting. Isotopic and geochemical signatures, particularly Sr/Y and Rb/Sr ratios and Eu anomalies, suggest that the syenogranites originated from a mixture of enriched mantle sources and crustal contributions, while the gabbronorites record a more primitive, weakly differentiated origin. Estimated thermodynamic emplacement conditions (700–850°C) and tectonic diagrams support a subduction setting followed by a syn- to post-collisional phase, consistent with the Pan-African dynamics along the southern margin of the Sahara Metacraton. Overall, this study demonstrates that the Niergui Massif exemplifies the complexity of Pan-African geodynamics, where mantle–crust interaction, partial melting, and magmatic fractionation played a key role in the formation of the basement. These results provide a robust framework for understanding the tectono-magmatic evolution of the Guéra region and pave the way for further investigations of the Sahara Metacraton.
Author Contributions
Guoldji Crepin Djamous: Conceptualization, Data curation, Formal Analysis, Investigation, Methodology, Resources, Visualization, Writing – original draft
Tassongwa Bernard: Conceptualization, Investigation, Methodology, Project administration, Resources, Supervision, Validation, Visualization, Writing – original draft, Writing – review & editing
Metang Victor: Conceptualization, Investigation, Project administration, Validation, Visualization, Writing – original draft, Writing – review & editing
Ngassam-Mbianya Ghislain: Conceptualization, Data curation, Formal Analysis, Methodology, Resources, Validation, Visualization, Writing – original draft
Tamen Jules: Conceptualization, Data curation, Formal analysis, Methodology, Resources, Validation, Visualization, Writing – original draft
Baïssemia Ronang Gustave: Investigation, Resources, Visualization, Writing – original draft
Jouanang Viclair Daina: Investigation, Resources, Visualization, Writing – original draft
Masonde Kouo Adelaïde Flore: Investigation, Resources, Writing – original draft
Bikaga Clarisse Rosine: Investigation, Resources, Writing – original draft
Nkoumbou Charles: Conceptualization, Project administration, Supervision
Funding
This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors.
Conflicts of Interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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    Djamous, G. C., Bernard, T., Victor, M., Ghislain, N., Jules, T., et al. (2026). Petrography and Geochemistry of Syenogranites and Gabbronorites from the Niergui Massif, Guéra Province, Chad. Earth Sciences, 15(2), 109-124. https://doi.org/10.11648/j.earth.20261502.13

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    Djamous, G. C.; Bernard, T.; Victor, M.; Ghislain, N.; Jules, T., et al. Petrography and Geochemistry of Syenogranites and Gabbronorites from the Niergui Massif, Guéra Province, Chad. Earth Sci. 2026, 15(2), 109-124. doi: 10.11648/j.earth.20261502.13

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    AMA Style

    Djamous GC, Bernard T, Victor M, Ghislain N, Jules T, et al. Petrography and Geochemistry of Syenogranites and Gabbronorites from the Niergui Massif, Guéra Province, Chad. Earth Sci. 2026;15(2):109-124. doi: 10.11648/j.earth.20261502.13

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  • @article{10.11648/j.earth.20261502.13,
      author = {Guoldji Crepin Djamous and Tassongwa Bernard and Metang Victor and Ngassam-Mbianya Ghislain and Tamen Jules and Baïssemia Ronang Gustave and Jouanang Viclair Daina and Masonde Kouo Adelaïde Flore and Bikaga Clarisse Rosine and Nkoumbou Charles},
      title = {Petrography and Geochemistry of Syenogranites and Gabbronorites from the Niergui Massif, Guéra Province, Chad},
      journal = {Earth Sciences},
      volume = {15},
      number = {2},
      pages = {109-124},
      doi = {10.11648/j.earth.20261502.13},
      url = {https://doi.org/10.11648/j.earth.20261502.13},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.earth.20261502.13},
      abstract = {The Niergui Massif, located at the southern margin of the Sahara Metacraton, represents a poorly documented portion of the Pan-African basement in Chad. This study integrates petrographic and geochemical analyses of syenogranites and gabbronorites to better constrain their nature, origin, and the magmatic processes involved in basement formation. The syenogranites are strongly potassic calc-alkaline, weakly peraluminous, and ferroan, whereas the gabbronorites are metaluminous and moderately differentiated. Major, trace, and rare-earth element geochemistry indicates a progressive magmatic evolution: gabbronorites reflect a primitive mantle source, while syenogranites show enrichment in incompatible elements and differentiation toward crustal magmas. Sr/Y and Rb/Sr ratios, as well as Eu anomalies, suggest that syenogranites formed from a mixture of enriched mantle and crustal sources, whereas gabbronorites are weakly differentiated and mantle-derived. Nb/Zr vs. Zr diagrams and zircon saturation temperatures (700–850°C) indicate that magma crystallization involved both fractional crystallization and partial melting. Tectonic discrimination diagrams (Ta vs. Yb, Rb vs. Yb+Ta) confirm a subduction setting followed by a syn- to post-collisional phase, consistent with the Pan-African dynamics between the Congo Craton and the Adamawa-Yadé block. These results indicate that the Niergui Massif exemplifies a bimodal magmatic system, characterized by mantle–crust interaction, partial melting, and fractional crystallization. The complexity of geochemical signatures reflects local variations and multiple stages of magmatic evolution from mantle to differentiated crustal magmas. This study provides a solid framework for understanding Pan-African geodynamics in the Guéra region and contributes to the characterization of the Neoproterozoic basement of the Sahara Metacraton.},
     year = {2026}
    }
    

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  • TY  - JOUR
    T1  - Petrography and Geochemistry of Syenogranites and Gabbronorites from the Niergui Massif, Guéra Province, Chad
    AU  - Guoldji Crepin Djamous
    AU  - Tassongwa Bernard
    AU  - Metang Victor
    AU  - Ngassam-Mbianya Ghislain
    AU  - Tamen Jules
    AU  - Baïssemia Ronang Gustave
    AU  - Jouanang Viclair Daina
    AU  - Masonde Kouo Adelaïde Flore
    AU  - Bikaga Clarisse Rosine
    AU  - Nkoumbou Charles
    Y1  - 2026/04/23
    PY  - 2026
    N1  - https://doi.org/10.11648/j.earth.20261502.13
    DO  - 10.11648/j.earth.20261502.13
    T2  - Earth Sciences
    JF  - Earth Sciences
    JO  - Earth Sciences
    SP  - 109
    EP  - 124
    PB  - Science Publishing Group
    SN  - 2328-5982
    UR  - https://doi.org/10.11648/j.earth.20261502.13
    AB  - The Niergui Massif, located at the southern margin of the Sahara Metacraton, represents a poorly documented portion of the Pan-African basement in Chad. This study integrates petrographic and geochemical analyses of syenogranites and gabbronorites to better constrain their nature, origin, and the magmatic processes involved in basement formation. The syenogranites are strongly potassic calc-alkaline, weakly peraluminous, and ferroan, whereas the gabbronorites are metaluminous and moderately differentiated. Major, trace, and rare-earth element geochemistry indicates a progressive magmatic evolution: gabbronorites reflect a primitive mantle source, while syenogranites show enrichment in incompatible elements and differentiation toward crustal magmas. Sr/Y and Rb/Sr ratios, as well as Eu anomalies, suggest that syenogranites formed from a mixture of enriched mantle and crustal sources, whereas gabbronorites are weakly differentiated and mantle-derived. Nb/Zr vs. Zr diagrams and zircon saturation temperatures (700–850°C) indicate that magma crystallization involved both fractional crystallization and partial melting. Tectonic discrimination diagrams (Ta vs. Yb, Rb vs. Yb+Ta) confirm a subduction setting followed by a syn- to post-collisional phase, consistent with the Pan-African dynamics between the Congo Craton and the Adamawa-Yadé block. These results indicate that the Niergui Massif exemplifies a bimodal magmatic system, characterized by mantle–crust interaction, partial melting, and fractional crystallization. The complexity of geochemical signatures reflects local variations and multiple stages of magmatic evolution from mantle to differentiated crustal magmas. This study provides a solid framework for understanding Pan-African geodynamics in the Guéra region and contributes to the characterization of the Neoproterozoic basement of the Sahara Metacraton.
    VL  - 15
    IS  - 2
    ER  - 

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Author Information
  • Department of Earth Sciences, University of Dschang, Dschang, Cameroon

  • Department of Earth Sciences, University of Dschang, Dschang, Cameroon

  • Department of Earth Sciences, University of Yaoundé 1, Yaoundé, Cameroon

  • Department of Earth Sciences, University of Dschang, Dschang, Cameroon

  • Department of Earth Sciences, University of Dschang, Dschang, Cameroon

  • Departement of Geological Engineering, University of Pala, Pala, Chad

  • Department of Earth Sciences, University of Yaoundé 1, Yaoundé, Cameroon

  • Department of Earth Sciences, University of Dschang, Dschang, Cameroon

  • Department of Earth Sciences, University of Yaoundé 1, Yaoundé, Cameroon

  • Department of Earth Sciences, University of Yaoundé 1, Yaoundé, Cameroon